I've done this before, and I'm about to tackle this on a screwed up post-war Mopar that had the battery relocated to the trunk. Not a Nova, but the concept is the same. I'm at the parts ordering phase for this one.
For fuses, there are two choices. The "Mega Fuse" style fuses go up to 300A, and 300A is generally enough for the starter cable. If you need more than 300A, there are "post fuses" (AKA "terminal fuses") that go on a 3/8" post. which are useful. Those are more common in marine applications, and can be found online.
Also, where the battery cable passes through a metal body panel, use a "pass through" connector. I prefer Moroso 74144, available at online speed shops (Summit, Jegs, Speedway Motors) or Amazon. If Red isn't your thing, it's available in black as Moroso 74145. The pass through is an excellent place to mount a terminal fuse block with a terminal fuse.
And be sure to put rubber boots on the cable ends, especially the ones under the car, exposed to weather.
You can power the fuse block(s) from the alterntor post, or from the starter post, but I prefer (a) separate MegaFuse(s) in the trunk, one for each fuse block, and separate power wires of appropriate size run from the megafuse near the battery (in the trunk) to each fuse block. This makes diagnostics easier down the road. I do generally run the alternator charge wire to the starter post, with a fusible link at the starter end of that cable, or a mega-fuse on the firewall sized to match the alternator. .